Россия
УДК 552.578 Углеводороды
Проведено литолого-геохимическое исследование артинских отложений и органического вещества, входящего в состав нефтегазоматеринских пород северной части Предуральского краевого прогиба Тимано-Печорской провинции. Породы очень разнообразны по составу (кластолиты, пелитолиты, карбонатолиты и микстолиты) и структурно-текстурным особенностям. В мелководно-морских обстановках (нижнемолассовые отложения) широко распространены микстолиты, с которыми связано смешанное гумусово-сапропелевое органическое вещество. Отмечается преобладание бедных и средних нефтегазоматеринских пород за счет увеличения гумусовой составляющей. Наилучшими генерационными показателями характеризуются микстолиты Кочмесской площади (HI — 240 мг УВ/г Сорг). Углепетрографические исследования указывают на преобладание битуминита (сапропелевая основа) в составе органического вещества, гумусовая составляющая доминирует в восточных районах, примыкающих к Уралу.
Предуральский краевой прогиб, артинские отложения, микстолиты, нефтематеринские породы, органическое вещество, битуминит, генерационный потенциал
Introduction
Currently, the problems of oil and gas bearing potential of foredeeps are relevant all over the world [1, 4, 5]. The studies of petroleum source rocks, assessment of their generation potential, transformation of organic matter (OM), characteristics of the lithological-facies features of petroleum source rocks and enclosing strata are carried out. Trough zones of fold-thrust areas in various regions of the world (Zagros fold system (Iran, Iraq), basins of Maturin (Venezuela), Chaco (Bolivia, Argentina), Llanos (Colombia), Tarim (China)) are among the largest areas in terms of oil and gas production [1, 3, 4].
The northern part of the Pre-Ural Foredeep and the adjacent areas of the western slope of the Urals are among the promising areas for prospecting and exploration for oil and gas in the Timan-Pechora province [9, 13]. Geological exploration surveys carried out here in recent years have discovered new oil deposits (Nersetinskoe), gas deposits (Levogrubeyuskoe) and new hydrocarbon deposits at known oilfields (Intinskoe) [9]. Limited knowledge of deep drilling and a complex tectonic structure are the main factors that restrain the active involvement of the territory in the exploration process. These negative factors also include poorly developed models of the structure and formation of promising sedimentary formations. The issues of depositional settings and facies modeling for this area are covered mainly in large generalizations for the Pechora Basin [8, 15]. Results of a comprehensive study of oil and gas content issues (source rock and enclosing strata estimates) of the Pre-Ural Foredeep are published [6, 7, 15]. One of the promising oil and gas bearing strata are Artinskian terrigenous deposits, which are part of the Permian (Upper Paleozoic) oil and gas complex. They are widespread in the north of the Pre-Ural Foredeep and are quite thick. This paper deals with the composition and structure of the Artinskian rocks, the hydrocarbon potential as well as considers the type OM of the petroleum source rocks.
Objects and research methods
The study area is located within the Pre-Ural Foredeep: the Chernyshev Ridge, Kosyu-Rogovaya and Korotaikha
Depressions. In total, the following nine well sections were studied: South-Stepkovozhskaya-1, Khosedayu-Neruyuskaya-6, Povarnitskaya-21, Bergantymylkskaya-1,3, Kochmesskaya-1,3, Middle-Kochmesskaya-2, Palnikshorskaya-1, and 2 outcrops along the Kozhim and Silovayaha rivers. The lithological and geochemical studies included the optical-microscopic method, complete chemical silicate analysis (wet), silicate X-ray fluorescence analysis and diffractometric analysis of clays. Petroleum source rocks were investigated by organic petrography as well as by organic geochemistry methods: organic carbon determination — Сorg, %; chloroform bitumoid — A-CBA, %; gas-liquid chromatography of the aliphatic fraction — GLC (Syktyvkar); Rock-Eval pyrolysis (Moscow, VNIGNI).
Results and discussion Material composition of the rocks
The Artinskian rocks are represented by clastolites, pelitolites, carbonatolites and mixtolites (rocks of mixed composition), formed in deep-water and shallow-water marine environments [6, 14]. In the east of the study area in the north of the Pre-Ural Foredeep, a deep-sea depression filled with terrigenous flysch sediments was formed in the Artinskian age. During the Artinskian stage, carbonate sedimentation continued in shallow-water shelf environment along the strike in a westerly direction, within the Kochmes area [8]. In the Late Artinskian – Early Kungurian time, terrigenous and terrigenous-carbonate deposits of the lower molasse accumulated everywhere in shallow-sea environments. The investigated well sections are represented mainly by coastal-marine sediments of the lower molasse; terrigenous flysch sediments were studied along the outcrops of the Kozhim and Silovayaha rivers. Artinskian molasse deposits are represented by a thin alternation of layers of predominantly mixed siliceous-terrigenous and carbonate compositions. The total thickness of the Artinskian deposits is greatest in the central parts of the Kosyu-Rogov Depression. The maximum thickness of flysch sediments is 1.5 km (increasing eastward), and the maximum thickness of gray-colored marine molasse is up to 3 km [6]. Assessment of the distribution of source rocks in the Artinskian complex, according to the data of average gamma-activity (well logging), showed that their greatest thickness is confined to the southern and southeastern parts of the Kosyu-Rogov Depression.
Artinskian rocks are diverse in composition as well as in structural and textural features. Table 1 shows brief characteristics of some types of rocks in the studied sections (Bergantymylkskaya, Padimeyskaya, Kochmesskaya, Povarnitskaya, Khosedayu-Neruyuskaya areas), which on the modular diagram [16] GM (hydrolyzate module) — Na2O + K2O (sum of alkalis) (Fig. 1, f) form 5 clusters (clusters No. I, II, III, IV, V). Outside the clusters, there are relatively clean carbonatolites (Povarnitskaya and Khosedayu-Neruyuskaya areas).
Organic matter composition and its hydrocarbon potential
Contemporary Corg (TOC) contents in clayey rocks of flysch deposits vary from 0.7% (Silovayaha River) to 3.7 % (Kozhim River), and has the range of 0.5–3.8 % in mudstones of terrigenous and terrigenous-carbonate molasses. According to organic petrography and geochemical studies, the OM contains producers of terrestrial and marine material (Fig. 2, a–c). In general, a zone with a similar mixed composition of OM (terrestrial and marine), which differs in the proportion of terrigenous components, is recognized in the Artinskian deposits. The lateral change in geochemical parameters occurs due to the catagenetic transformations of OM from the southern part of the Kosyu-Rogovaya depression to the northeast of the Korotaikha Depression.
Rock-eval data indicate a change in the values of the hydrogen index (HI, mg HC/g TOC) in a wide range from the first tens to 240 (Fig. 2, h). The decrease in the generation rate is due to a large proportion of terrigenous detrite. Higher HI values — 215–240 mg HC/g TOC were found in shallow-water shelf mixtoliths and carbonatolites of the Kochmes area (clusters I — III), where the proportion of terrigenous components in OM is reduced and prevails the bituminite, a structureless marine type substance (Fig. 2).
In comparison with the entire Permian terrigenous complex on the studied territory, the Artinskian deposits, which contain predominantly marine OM, have an initially higher hydrocarbon (oil) potential. The Kungurian coal-bearing strata generally have a low hydrocarbon potential [11, 12]. Increased values are only noted in local areas of the northern regions (Vorkutsky), where the proportion of liptinite components in the OM increases [10–12]. The total assessment of the possible hydrocarbon generation of an oil character will be significantly higher in the Artinskian complex than in the coal-bearing one due to the predominance of type I–II of the initial OM and catagenetic transformation sufficient for fluid generation.
According to the published data, the catagenetic transformation of the OM of the Artinskian deposits increases towards the Ural folded structure. The maturity of OM varies from gradations of MC1–MC2 on the western side of the Kosyu-Rogov Depression to gradations AC1–2 on its eastern side and in the Korotaikha Depression [6]. The organic petrography and Rock-eval data carried out indicate the unfinished generation of hydrocarbons in the Artinskian deposits of the Kochmesskaya, Khosedayu-Neruyuskaya, Bergantymylkskaya, Padimeyskaya and South-Stepkovozhskaya areas, where these deposits have not yet left the oil window zone (catagenesis gradation, MC2).
In the indicated areas, in various types of rocks the active release of bitumen (Bit) from bituminite (Lbit) is very clearly visible (Fig. 2, d, e). In the zone of higher maturity (Ro > 0.85 %, MC3 gradation) in the Kozhimskaya and Middle-Kochmesskaya areas, bituminous smears and excretions from OM are not observed, bituminite has a residual appearance, and the bulk of the rock is represented by terrigenous detrite (vitrinite and inertinite Fig. 2, d, f, g). The main generation of hydrocarbons from the Artinskian formations source rocks within the eastern part of the Kosyu-Rogov Depression has been completed. The latter is confirmed by the level of OM maturity and the earlier estimate of the generation time by petroleum source rocks of the Pre-Ural Foredeep [6].
Conclusions
The Artinskian rocks of the north of the Pre-Ural Foredeep are very diverse in composition and structural and textural features. A wide distribution of shallow-marine mixtoliths was revealed in the lower molasse, in which a mixed terrestrial and marine OM predominates. It was established the presence of poor and fair petroleum source rocks, the hydrogen index varies from a few tens to 240 mg HC/g TOC. A decrease in the generation rate occurs due to a large proportion of terrigenous detrite in the OM. The highest HI values, 240 mg HC/g TOC, were found in the mixtoliths of the Kochmesskaya area, where bituminite (marine components) predominates in the OM.
1. Bullock L., Parnell J., Muirhead D., Armstrong J., Schito A., Corrado S. A thermal maturity map based on vitrinite reflectance of British coals. Journal of the Geological Society. V. 176, 2019, pp. 1136-1142. https://doi.org/10.1144/jgs2019-055.
2. Danham R. J. Classification of carbonate rock according to depositional texture. Classification of carbonate rock. Simposium Amer. Assoc. Petrol. Geol. Mem (Ed. by Ham V E), V. 1, 1962, pp. 108-121.
3. Mora A. Petroleum systems of the Eastern Cordillera, foothill basins, and associated Llanos basin: Impacts on the prediction of large scale foreland and foothill petroleum accumulations. AAPG Bulletin, V. 99, No. 8, 2015, pp. 1401-1406. DOIhttps://doi.org/10.1306/bltninto032615.
4. Opera A., Alizadeh B., Sarafdokht H., Janbaz M., Fouladvand R., Heidarifard M. H. Burial history reconstruction and thermal maturity modeling for the middle cretaceous-early Miocene petroleum system, southern dezful embayment, SW Iran. International Journal of Coal Geology, V. 120, 2013. pp. 1-14. DOIhttps://doi.org/10.1016/j.coal.2013.08.008.
5. Pitman J. K., Steinshouer D., Lewan M. D. Petroleum generation and migration in the Mesopotamian Basin and Zagros Fold Belt of Iraq: results from a basin-modeling study. GeoArabia-Manama, V. 9, No. 4, 2004, pp. 41-72. DOIhttps://doi.org/10.2113/geoarabia090441.
6. Anischenko L. A., Klimenko S. S., Ryabinkina N. N., Malyshev N. A., Ryabinkin S. V., Kuplevich I. L., Zakharov A. A., Prozorov S. F., Antonov V. I., Ivanov V. V., Kuznetsov N. I., Yudin V. M. Organıcheskaıa geohımııa ı neftegazonosnost permskıh otlojenıı severa Predýralskogo progıba (Organic geochemistry and oil and gas-bearing of the Permian depositss in the north of the Pre-Ural foredeep). Saint Petersburg: Nauka, 2004, 214 p.
7. Bazhenova T. K., Shimansky V. K., Vasilieva V. F., Shapiro A. I., Yakovleva (Gembitskaya) L. A., Klimova L. I. Organıcheskaıa geohımııa Tımano-Pechorskogo basseına (Organic geochemistry of the Timan-Pechora basin). Saint Petersburg: VNIGRI, 2008, 164 p.
8. Galkina L. V. Karta lıtofatsıı artınskogo ıarýsa nıjneı permı (Map of lithofacies of the Artinskian stage of the Lower Permian). Timan-Pechora sedimentary basin: Atlas of geological maps. Ukhta: TP SIC, 2000, 64 p.
9. Danilov V. N. Grıada Chernysheva: geologıcheskoe stroenıe ı neftegazonosnost (Chernysheva Ridge: geological structure and oil and gas content). Saint Petersburg: Renome, 2017, 288 p.
10. Kotik O. S., Kotik I. S., Kargieva T. G. Permskiye otlozheniya yugo-vostoka Korotaikhinskoy vpadiny: uglepetrografiya, geokhimiya i neftegazogeneratsionnyi potentsial (Permian deposits in the southeast of Korotaihinsky depression: coalpetrography, geochemistry and hydrocarbon potential). Geologiya nefti i gaza, 2017, V. 4, pp. 91-102.
11. Kotik O. S., Valyaeva O. V. Organic matter and geochemistry of Kungurian coals from Northern Pre-Ural Foredeep. Georesursy, 2017, V. 19, No. 2, pp. 117-121. DOI http://doi.org/10.18599/grs.19.2.5
12. Kotik O. S., Valyaeva O. V. Tipy organicheskogo veshchestva i generatsionnyy potentsial kungurskikh terrigennykh otlozheniy severa Predural'skogo krayevogo progiba (Types of organic matter and generation potential of kungurian terrigenous deposits of Pre-Ural Foredeep). Georesursy, 2014, V. 2, No. 57, pp. 51-55. DOI http://dx.doi.org/10.18599/grs.57.2.7
13. Nikonov N. I. Skladchato-nadvigovyye zony neftegazonakopleniya Timano-Pechorskoy provintsii i problemy ikh osvoyeniya (Fold overthrust accumulation zone of the Timan-Pechora province and problems of their development). Nedropol'zovaniye XXI vek, 2013, V. 4, No. 41, pp. 46-50.
14. Saldin V. A. Novye dannye po geologıı nıjnepemskıh otlojenıı r. Kojym (Prıpolıarnyı Ýral) (New data on the geology of the Lower Phemian deposits of the r. Kozhym (Subpolar Urals)). Lithogenesis and geochemistry of sedimentary formations of the Timan-Ural region, 2002, No. 4, pp. 11-33.
15. Teplov E. V., Larionova Z. V., Beda I. Yu., Dovzhikova E. G., Kuranova T. I., Nikonov N. I., Petrenko E. L., Shabanova G. A. Prirodnyye rezervuary neftegazonosnykh kompleksov Timano-Pechorskoy provintsii (Natural reservoirs of oil and gas complexes of the Timan-Pechora province) GUP RK TP SIC. Saint-Petersburg: Renome, 2011, 286 p.
16. Yudovich Ya. E. and Ketris M. P. Osnovy litokhimii (Fundamentals of lithochemistry). Saint Petersburg: Nauka, 2000, 479 p.
